Some Important Compounds of Transition Metals

On oxidation of ${\mathrm{S}}_{\mathrm{2}}{\mathrm{O}}_3^{2-}$ by ${\mathrm{MnO}}_4^{-}$  in neutral aqueous medium, the oxidation number of S would change from:

The number of moles of ${\mathrm{KMnO}}_4$ that will be needed to react with one mole of sulphite ion in acidic solution is:

The following steps are involved in the manufacturing of potassium dichromate:

What is the difference in the oxidation number of $\mathrm{Cr}$ between X and Y?

What is the colour change when solid potassium dichromate is heated with concentrated sulphuric acid?

Solid potassium dichromate when heated with concentrated sulphuric acid gives which of the following product?

${\mathrm{K}}_2{\mathrm{Cr}}_2{\mathrm{O}}_7$  when reacts with cold conc. ${\mathrm{H}}_2{\mathrm{SO}}_4$ gives red crystal of

Which of the following product is not formed when potassium dichromate reacts with cold sulphuric acid?

The fusion of chromite ore $\left({\mathrm{FeCr}}_2{\mathrm{O}}_4\right)$ with ${\mathrm{Na}}_2{\mathrm{CO}}_3$ in air gives a yellow solution upon addition of water. Subsequent treatment with ${\mathrm{H}}_2{\mathrm{SO}}_4$ produces an orange solution. The yellow and orange colours, respectively, are due to the formation of

What is the melting point of potassium dichromate?

Which of the following statements is correct about tetrahedral manganate and permanganate ions?

Which of the following statements is/are false?

A solution of ${\mathrm{KMnO}}_4$ is reduced to various products depending upon its $\mathrm{pH}$.

$\mathrm{I}.$ At $\mathrm{pH}<7$, it is reduced to a colourless solution ($\mathrm{A}$).

$\mathrm{II}.$ At $\mathrm{pH}=7$, it forms a brown precipitate ($\mathrm{B}$).

$\mathrm{III}.$ At $\mathrm{pH}>7$, it gives a green solution ($\mathrm{C}$).

Then $\mathrm{A}, \mathrm{B}$ and $\mathrm{C}$, respectively are

Which of the following sodium salts, on heating with solid  ${\mathrm{K}}_2{\mathrm{Cr}}_2{\mathrm{O}}_7$  and concentrated ${\mathrm{H}}_2{\mathrm{SO}}_4$, gives red vapour?

Which of the following statements is incorrect regarding the similarities between hexavalent nature of $\mathrm{Cr}$ and $\mathrm{S}$ compounds?

Which of the following species has oxygen in $-1$ oxidation state?

When chromite ore is fused in strong alkali in presence of air, the number of equivalent bond lengths in anionic part of $\mathrm{Cr}$-containing product is $\mathrm{x}.$

Find the value of $\mathrm{x}.$

Number of reactions in which ${\mathrm{MnO}}_2$ will be formed as one of the product-

(i) ${\mathrm{KMnO}}_4\stackrel{\mathrm{\Delta }}{⟶}$

(ii) ${\mathrm{S}}^{-2}+{\mathrm{MnO}}_4^{-1}+{\mathrm{H}}^{+}⟶$

(iii) ${\mathrm{MnO}}_4^{-1}+{\mathrm{Mn}}^{+2}+{\mathrm{H}}_2\mathrm{O}\stackrel{{\mathrm{ZnSO}}_4}{⟶}$

(iv) ${\mathrm{K}}_2\mathrm{Mn}{\mathrm{O}}_4\stackrel{{\mathrm{H}}^{+}}{⟶}$

(v) ${\mathrm{Mn}}^{+2}+{\mathrm{S}}_2{\mathrm{O}}_8^{-2}+{\mathrm{H}}_2\mathrm{O}⟶$

(vi) ${\mathrm{MnO}}_4^{-1}+{\mathrm{S}}_2{\mathrm{O}}_3^{-2}+{\mathrm{H}}_2\mathrm{O}\stackrel{{\mathrm{OH}}^{-}}{⟶}$

(vii) ${\mathrm{NO}}_2^{-1}+{\mathrm{MnO}}_4^{-1}+{\mathrm{H}}^{+}⟶$

(viii) ${\mathrm{MnO}}_4^{-1}+{\mathrm{H}}_3{\mathrm{O}}^{+}+{\mathrm{I}}^{-}⟶$